Premium
On the nature of L UNDEL and K NOWLES rhenide ion
Author(s) -
Ginsberg A. P.,
Koubek E.
Publication year - 1962
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19623150506
Subject(s) - rhenium , perrhenate , alkali metal , hydride , inorganic chemistry , aqueous solution , chemistry , ion , metal , organic chemistry
Evidence is presented showing that the assumption that LUYUELL and KNOWLES rhenide is identical with the product obtained by reducing aqueous perrhenate with an alkali metal, recently shown to be a hydride, is incorrect. Absorption spectra of acid rhenide solutions show that. a complex of Re‐ cannot be present, and so it is concluded that rhenide is a hydride complex of rhenium different, from that obtained by reduction with alkali metals.