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Polarography of Ti. II. Studies of reversibility of Ti III and Ti IV in acid sulphate medium
Author(s) -
Habashy G. M.
Publication year - 1960
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19603060511
Subject(s) - polarography , chemistry , inorganic chemistry , hydrolysis , anode , electrode , organic chemistry
The polarographic reversibility of the Ti 3+ /Ti 4+ couple has been discussed the conditions of reversibility have been established and confirmed by several polarographic techniques. The reversible waves, anodic or cathodic are due respectively to the oxidation and reduction of hydrated sulphate complexes, viz.. Irreversibility is due to the formation of some hydrolysed sulphate complexes.