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Fluoberyllates and their Analogy with Sulphates. XII. Complex Compounds of Zinc and Cadmium Fluoberyllate with Organic Bases
Author(s) -
Kanti Ghosh Amiya,
Nath Ráy Nirmalendu
Publication year - 1959
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19593000112
Subject(s) - cadmium , zinc , chemistry , ethylenediamine , metal , organic base , base (topology) , inorganic chemistry , nuclear chemistry , organic chemistry , mathematical analysis , mathematics
A few complex compounds of zinc and cadmium fluoberyllates with organic base were prepared. [Zn en 3 ]BeF 4 and [Cd en 3 ]BeF 4 were prepared by the addition of a concentrated solution of ethylenediamine to the concentrated solution of metal fluoberyllates. [Zn pn 3 ]BeF 4 was also isolated. The corresponding cadmium compound, however could not be prepared. ZnBeF 4 , C 6 H 12 N 4 , 8 H 2 O and CdBeF 4 , C 6 H 12 N 4 , 8 H 2 O were also prepared by following similar methods. In chemical compositions and also in their chemical properties these compounds resembles the corresponding sulphate compounds.