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Fluoberyllates of Organic Bases. I
Author(s) -
Ghosh Amiya Kanti
Publication year - 1959
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19593000110
Subject(s) - benzidine , ethylene diamine , diamine , chemistry , ethylene , ammonium , thermal stability , polymer chemistry , organic base , medicinal chemistry , nuclear chemistry , organic chemistry , catalysis
Abstract Fluoberyllates of organic bases have been prepared. Ethylene diamine fluoberyllate NH 2 · CH 2 · CH 2 · NH 2 , H 2 BeF 4 , propylenediamine fluoberyllate NH 2 · CH · (CH 3 ) · CH 2 · NH 2 , H 2 BeF 4 and benzidine fluoberyllate NH 2 · C 6 H 4 · C 6 H 4 · NH 2 , H 2 BeF 4 were prepared by the addition of these organic bases on a concentrated solution of ammonium fluoberyllate. These crystalline compounds were found to be stable. Benzidine fluoberyllate like benzidine sulphate is insoluble in water. The X‐ray diffraction spectra of ethylene‐diamine fluoberyllate and ethylene‐diamine sulphate were taken and these compounds were proved to be isomorphous. The thermal stability of ethylene diamine fluoberyllate has also been studied.