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A study on the formation of complex compounds between bivalent and univalent salts in solution. Systems: CdBr 2 KBrH 2 O and CdI 2 KIH 2 O
Author(s) -
Aggarwal R. C.
Publication year - 1958
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19582970108
Subject(s) - chemistry , conductivity , conductance , complex formation , ion , inorganic chemistry , bivalent (engine) , cadmium , crystallography , stereochemistry , analytical chemistry (journal) , metal , chromatography , mathematics , combinatorics , organic chemistry
Studies of conductivity, freezing point depression and p H indicate the existence of the complex compounds K 2 [CdBr 4 ] and K 2 [CdI 4 ] in the systems: CdBr 2 KBrH 2 O and CdI 2 KIH 2 O respectively. Negative values of transference number of cadmium ion and the marked deviations of conductance from the additivity observed in the system: CdI 2 KIH 2 O, show that the complex K 2 [CdI 4 ] indicated by the physico‐chemical properties is quite stable.