Tristrifluoromethyl Antimonic Acid and its Derivatives | Zendy

Eneléus H. J. | Zendy; Moss J. H. | Zendy

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Tristrifluoromethyl Antimonic Acid and its Derivatives

Author(s) -

Eneléus H. J.,

Moss J. H.

Publication year - 1955

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.19552820106

Subject(s) - monobasic acid , hydrobromic acid , chemistry , hydrochloric acid , salt (chemistry) , antimony , pyridinium , hydrolysis , medicinal chemistry , alkaline hydrolysis , inorganic chemistry , organic chemistry

Tristrifluoromethyl antimony dichloride, (CF 3 ) 3 SbCl 2 , reacts with water to give mono‐ and dihydrates. A solution of tristrifluoromethyl antimonic acid H(CF 3 ) 3 Sb(OH) 3 may also be isolated. It is a strong monobasic acid which is fairly stable to alkaline hydrolysis. The pyridinium salt has been isolated and with hydrochloric and hydrobromic acids gives derivatives of the type C 5 H 5 NH(CF 3 ) 3 SbX 3 (X = Cl, Br).

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