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Incongruent dissolution of chromite in lithium tetraborate flux
Author(s) -
Merkle Roland K. W.,
Loubser Maggi,
Gräser Peter P. H.
Publication year - 2004
Publication title -
x‐ray spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.447
H-Index - 45
eISSN - 1097-4539
pISSN - 0049-8246
DOI - 10.1002/xrs.759
Subject(s) - chromite , dissolution , chromium , flux (metallurgy) , lithium (medication) , metallurgy , materials science , magnesium , phase (matter) , mineral , aluminium , chemistry , inorganic chemistry , medicine , organic chemistry , endocrinology
During lithium tetraborate fluxing, chromite undergoes incongruent dissolution, in which high proportions of aluminium, magnesium and titanium are dissolved in the flux while some iron remains behind in a residual chromium‐rich phase. Increasing the time and flux/sample ratio improve the dissolution of chromite. Errors in XRF analysis due to incomplete dissolution of chromite in lithium tetraborate flux will have the largest effects for chromium and lesser, although still serious, effects for iron. Copyright © 2004 John Wiley & Sons, Ltd.