Chemical effect on intensity ratios of K‐series x‐rays in vanadium, chromium and manganese compounds | Zendy

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Chemical effect on intensity ratios of K‐series x‐rays in vanadium, chromium and manganese compounds

Author(s) -

Tamaki Yoichi

Publication year - 1995

Publication title -

x‐ray spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.447

H-Index - 45

eISSN - 1097-4539

pISSN - 0049-8246

DOI - 10.1002/xrs.1300240504

Subject(s) - manganese , vanadium , chromium , series (stratigraphy) , intensity (physics) , chemistry , materials science , inorganic chemistry , radiochemistry , metallurgy , optics , physics , geology , paleontology

Kα and Kβ x‐ray fluorescence spectra of various V, Cr and Mn compounds were measured with a Bragg spectrometer. The relative intensities of the Kβ 1,3 , Kβ 2 , Kβ′ and Kβ″ lines with respect to the Kα line were determined to confirm the chemical effect on the Kβ/Kα intensity ratio obtained using a Si(Li) detector. Chemical effects on each component line are discussed with respect to the oxidation state of the metal ions. The relative importance of an increase in transition probabilities of the Kβ 2 group (Kβ 2 and Kβ″) was evaluated in the determination of the overall Kβ/Kα ratio.

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