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Kβ/Kα ratios and chemical effects in partially filled 3d‐shell elements
Author(s) -
Raghavaiah C. V.,
Rao N. Venkateswara,
Sree Murty G. Krishna,
Rao M. V. S. Chandrasekhar,
Reddy S. Bhuloka,
Sastry D. L.
Publication year - 1992
Publication title -
x‐ray spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.447
H-Index - 45
eISSN - 1097-4539
pISSN - 0049-8246
DOI - 10.1002/xrs.1300210508
Subject(s) - electron shell , shell (structure) , resolution (logic) , atom (system on chip) , analytical chemistry (journal) , materials science , high resolution , chemistry , atomic physics , physics , ion , remote sensing , organic chemistry , chromatography , artificial intelligence , computer science , embedded system , composite material , ionization , geology
The dependence of the Kβ/Kα ratio on the chemical constitution of the x‐ray emitting atom of 3d‐shell elements. V, Cr, Mn and Fe, was studied employing a high‐resolution Si(Li) detector. A maximum deviation of 9% in the Kβ/Kα ratio for the elements V and Mn is found when compared with their respective compounds. The experimental results are found to be consistent with the theoretical values due to Brunner's model.