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Novel method for estimation of the effective nuclear charge ( Z eff ) on the metal atom on cobalt complexes from the x‐ray absorption discontinuity
Author(s) -
Khadikar Padmakar V.
Publication year - 1991
Publication title -
x‐ray spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.447
H-Index - 45
eISSN - 1097-4539
pISSN - 0049-8246
DOI - 10.1002/xrs.1300200205
Subject(s) - cobalt , atom (system on chip) , discontinuity (linguistics) , metal , x ray , absorption (acoustics) , atomic physics , effective nuclear charge , chemistry , materials science , analytical chemistry (journal) , physics , nuclear physics , inorganic chemistry , optics , ion , mathematics , mathematical analysis , chromatography , computer science , embedded system , organic chemistry
A novel method for estimation of the effective nuclear charge ( Z eff ) on the central metal atom in cobalt complexes from the x‐ray K‐absorption discontinuity is proposed. Its potential is discussed on the basis of statistical analysis of the data obtained from the results for 25 cobalt complexes which indicated fairly good agreement between the observed and the estimated values of Z eff for the cobalt atom.