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X‐ray K emission spectra of vanadium in various oxidation states
Author(s) -
Yasuda S.,
Kakiyama H.
Publication year - 1978
Publication title -
x‐ray spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.447
H-Index - 45
eISSN - 1097-4539
pISSN - 0049-8246
DOI - 10.1002/xrs.1300070108
Subject(s) - vanadium , oxidation state , spectral line , atom (system on chip) , analytical chemistry (journal) , x ray , single crystal , chemistry , emission spectrum , crystallography , materials science , inorganic chemistry , metal , physics , optics , metallurgy , chromatography , astronomy , computer science , embedded system
The Kα 1,2 , Kβ 1,3 , Kβ 5 , and Kβ″ emission spectra of vanadium in the element and several V (III), V(IV), and V(V) compounds have been measured with a two‐crystal X‐ray spectrometer. The Kα 1 and Kβ 1,3 peaks shift slightly to lower energies with increasing lthe oxidation state of vanadium atom and the Kβ 5 peak shifts to higher with it. An approximately linear relationship between Kα 1 width and Kα 1 /Kα 2 intensity ratio can be used for lindentification of vanadium oxidation state.