The effect of oxidation state on the intensities of Kβ 5  and Kβ″ of 3d‐transition elements | Zendy

Asada E. | Zendy; Takiguchi T. | Zendy; Suzuki Y. | Zendy

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The effect of oxidation state on the intensities of Kβ 5 and Kβ″ of 3d‐transition elements

Author(s) -

Asada E.,

Takiguchi T.,

Suzuki Y.

Publication year - 1975

Publication title -

x‐ray spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.447

H-Index - 45

eISSN - 1097-4539

pISSN - 0049-8246

DOI - 10.1002/xrs.1300040408

Subject(s) - oxidation state , transition metal , atom (system on chip) , oxide , intensity (physics) , analytical chemistry (journal) , metal , chemistry , crystal (programming language) , materials science , crystallography , optics , metallurgy , physics , catalysis , biochemistry , programming language , chromatography , computer science , embedded system

Using a commercially available flat crystal spectrometer in a slightly modified form, an investigation was made of the peak intensity ratios (Kβ 5 /Kβ 1 ) and the relative intensities of Kβ″ to Kβ 5 in different oxidation states of 3d‐transition metal atoms existing in forms of oxidic compounds. The peak intensity ratios (Kβ 5 /Kβ 1 ) for V, Cr, Mn, Fe, Co, Ni and Cu, as well as the peak profiles of Kβ″ and Kβ 5 for V, Cr and Mn, were investigated. Results suggest that changes in the intensities of the Kβ 5 and Kβ″ bands can be applied to determining the oxidation number of a metal atom in its oxide.

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