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Study on the Use of Rare Earth Stabilizer as Poly(Vinyl Chloride) Stabilizer
Author(s) -
Liu Zhaogang,
Fan Junwei,
Feng Jiameng,
Li Mei,
Hu Yanhong,
Hao Wei,
Feng Fushan
Publication year - 2020
Publication title -
journal of vinyl and additive technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.295
H-Index - 35
eISSN - 1548-0585
pISSN - 1083-5601
DOI - 10.1002/vnl.21768
Subject(s) - stabilizer (aeronautics) , zinc stearate , calcium stearate , thermal stability , lanthanum , materials science , stearate , compounding , cerium , composite number , vinyl chloride , zinc , nuclear chemistry , inorganic chemistry , polymer chemistry , chemistry , raw material , composite material , organic chemistry , metallurgy , polymer , mechanical engineering , copolymer , engineering
Lanthanum aminobenzoate (LAB), cerium aminobenzoate (CAB), and lanthanum and cerium aminobenzoate (LCAB) were synthesized with p ‐aminobenzoic acid, lanthanum nitrate, or cerium nitrate as raw materials to study the influence of different rare earth elements on the stability of rare earth stabilizers. The thermal stability of by CAB, LCAB, and LAB toward poly(vinyl chloride) (PVC) was studied. The results of Congo red test and thermal aging test showed when three rare earth stabilizers acted independently, the advantages and disadvantages of thermal stability are as follows: LAB > CAB > LCAB. However, in compound experiments, the thermal stability of composite stabilizers compounded by CAB or LCAB with zinc stearate, calcium stearate, or pentaerythritol (PE) was slightly better than that of composite stabilizers compounded by LAB. Among of them, when the compounding scheme was LCAB:zinc stearate:PE = 1:1:3, the thermal stability time reached 60 minutes; CAB:zinc stearate:PE = 1:1:3, the thermal stability time reached 50 minutes, compared with the rare earth stabilizer alone, the composite thermal stabilizer gave PVC samples better antidiscoloration performance and longer thermal stability time.