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Degradability in a natural compost medium of (linear low‐density polyethylene)/(soya powder) blends compatibilized with epoxidized natural rubber
Author(s) -
Sam S.T.,
Ismail H.
Publication year - 2014
Publication title -
journal of vinyl and additive technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.295
H-Index - 35
eISSN - 1548-0585
pISSN - 1083-5601
DOI - 10.1002/vnl.21338
Subject(s) - crystallinity , linear low density polyethylene , materials science , ultimate tensile strength , natural rubber , compost , composite material , polyethylene , degradation (telecommunications) , elongation , waste management , telecommunications , computer science , engineering
The objective of this study was to investigate the degradability of linear low‐density polyethylene (LLDPE)/(soya powder) blends. The blends were compatibilized by epoxidized natural rubber with 50 mol% of epoxidation. They were exposed to a natural compost medium located in northern Malaysia. The degradability was evaluated by using tensile tests, a morphological study, carbonyl indices, crystallinity measurements, weight loss, and molecular‐weight changes. The tensile strength and elongation at break of the compatibilized blends decreased during one year of exposure. The colonization of fungus and the formation of pores were observed in micrographs. The carbonyl indices, crystallinity, and weight loss increased during exposure, thereby indicating the degradation of the blends. The reduction in molecular weight revealed the degradation of the LLDPE upon composting. Surprisingly, after composting, the compatibilized blends showed more degradation than the uncompatibilized ones. J. VINYL ADDIT. TECHNOL., 20:42–48, 2014. © 2014 Society of Plastics Engineers