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Some aspects of the thermal degradation of PVC. Crosslinking of macromolecules
Author(s) -
Yanborisov V. M.,
Minsker K. S.,
Zaikov G. E.,
Zaikov V. G.
Publication year - 2002
Publication title -
journal of vinyl and additive technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.295
H-Index - 35
eISSN - 1548-0585
pISSN - 1083-5601
DOI - 10.1002/vnl.10360
Subject(s) - macromolecule , degradation (telecommunications) , materials science , thermal , conjugated system , chemical engineering , polymer chemistry , polymer , chemistry , composite material , thermodynamics , computer science , telecommunications , biochemistry , physics , engineering
Direct experimental proof is presented that crosslinking of macromolecules during the thermal degradation of PVC proceeds with participation of blocks of conjugated double bonds formed upon activation by carbonylallyl groups.