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Degradation and stabilization of poly(vinyl chloride). 6: Model studies on dehydrochlorination of 6(4)‐chloro‐4(5)‐tetradecenes in the presence of alkyl phosphites and zinc di(dialkyl phosphites)
Author(s) -
Fisch Michael H.,
Bacaloglu Radu
Publication year - 1999
Publication title -
journal of vinyl and additive technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.295
H-Index - 35
eISSN - 1548-0585
pISSN - 1083-5601
DOI - 10.1002/vnl.10334
Subject(s) - alkyl , degradation (telecommunications) , zinc , vinyl chloride , chemistry , polymer chemistry , nuclear magnetic resonance spectroscopy , materials science , organic chemistry , polymer , copolymer , telecommunications , computer science
Thermal dehydrochlorination of trans ‐6(4)‐chloro‐4(5)‐tetradecenes, models for PVC degradation, was studied by NMR spectroscopy both alone and in the presence of alkyl and zinc phosphites. The implications of these results on PVC degradation and stabilization are discussed.