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Photoluminescent properties of flexible PVC compounds and their interpretation for performance analysis of automotive exterior parts
Author(s) -
Kann Yelena,
Billingham Norman C.
Publication year - 2003
Publication title -
journal of vinyl and additive technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.295
H-Index - 35
eISSN - 1548-0585
pISSN - 1083-5601
DOI - 10.1002/vnl.10056
Subject(s) - asphalt , materials science , photobleaching , degradation (telecommunications) , fluorescence , composite material , colored , photoluminescence , optoelectronics , computer science , optics , telecommunications , physics
Abstract Study of fluorescence emission from flexible PVC‐based formulations, colored by exposure to road asphalt or degraded thermally or by UV aging, shows that fluorescent species are formed during the interaction of PVC with road asphalt. For the conditions found in exterior automotive applications, no other known degradation causes development of fluorescence. Flexible PVC‐based formulations discolored by asphalt staining or degraded thermally at moderate temperatures bleach completely under conditions of natural or artificial weathering. A simple technique, using visually observed photoluminescence and photobleaching, can thus identify photoactive groups formed during the interaction of PVC with road asphalt. Application of this test method will allow selective improvement of failed asphalt resistance without treating the “overall” stability of a compound.