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A Parisian Vision of the Chemistry of Hypercoordinated Silicon Derivatives
Author(s) -
Lemière Gilles,
Millanvois Alexandre,
Ollivier Cyril,
Fensterbank Louis
Publication year - 2021
Publication title -
the chemical record
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.61
H-Index - 78
eISSN - 1528-0691
pISSN - 1527-8999
DOI - 10.1002/tcr.202100049
Subject(s) - silicon , chemistry , molecule , combinatorial chemistry , nanotechnology , photochemistry , organic chemistry , materials science
Less than ten years of acquaintance with hypercoordinated silicon derivatives in our lab is described in this account. Martin's spirosilane derivatives open new opportunities as ligands and as agents for the activation of small molecules and bis‐catecholato silicates have proven to be exquisite radical precursors in photoredox conditions for broad synthetic applications.