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Natural Cellulose Derived Nanocomposites as Anodic Materials for Lithium‐Ion Batteries
Author(s) -
Lin Zehao,
Li Shun,
Huang Jianguo
Publication year - 2020
Publication title -
the chemical record
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.61
H-Index - 78
eISSN - 1528-0691
pISSN - 1527-8999
DOI - 10.1002/tcr.201900030
Subject(s) - nanocomposite , cellulose , materials science , oxide , anode , lithium (medication) , nanofiber , chemical engineering , filter paper , metal , metal ions in aqueous solution , cellulose fiber , porosity , nanotechnology , fiber , electrode , composite material , chemistry , metallurgy , medicine , endocrinology , engineering
Bio‐inspired synthetic method provides an effective shortcut to fabricate functional nanostructured materials with specific morphologies and designed functionalities. Natural cellulose substances (e. g., commercial laboratory cellulose filter paper) possesses unique three‐dimensionally cross‐linked porous structures and abundant functional groups for the functional modification on the surfaces. The deposition of metal oxide gel film on the surfaces of the cellulose nanofibers is facilely to be achieved through the surface sol‐gel process, resulting in metal oxide replicas of the initial cellulose substance or metal‐oxide/carbon nanocomposites. Moreover, the as‐deposited metal oxide gel films coated on the cellulose fiber surfaces provide ideal platforms for the further formation of specific functional assemblies, and eventually to the corresponding nanocomposite materials. Based on this methodology, various nanostructured composites were prepared and employed as anodic materials for lithium‐ion batteries, including metal‐oxides‐based (such as SnO 2 , TiO 2 , MoO 3 , Fe x O y , and SiO 2 ) and Si‐based composites, as summarized in this personal account. Benefiting from the unique hierarchically porous network structures and the synergistic effects among the composite components of the anodic materials, the transfer of electrons/ions is accelerated and the structural stability of the electrode is enhanced, leading to the improved lithium storage performances and promoted cycling stability.