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Electrochemically Induced Diels‐Alder Reaction: An Overview
Author(s) -
Heravi Majid M.,
Zadsirjan Vahideh,
Kouhestanian Elham,
AlimadadiJani Behnoush
Publication year - 2020
Publication title -
the chemical record
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.61
H-Index - 78
eISSN - 1528-0691
pISSN - 1527-8999
DOI - 10.1002/tcr.201900018
Subject(s) - pericyclic reaction , cycloaddition , cyclohexene , alkene , diels–alder reaction , chemistry , diene , derivative (finance) , organic chemistry , electrosynthesis , combinatorial chemistry , catalysis , electrochemistry , natural rubber , electrode , financial economics , economics
One of the most important name reactions in organic chemistry, is the Diels‐Alder cycloaddition reaction. It is a chemical reaction between a conjugated diene and a substituted alkene, commonly termed the dienophile to construct a substituted cyclohexene derivative. It is the stereotypical example of a pericyclic reaction with a concerted mechanism. In synthesis, the use of electricity instead of stoichiometric amounts of oxidant or reducing agents is definitely appealing for economic, ecological and selective, reasons. In this review, we try to underscore the combination of the electrosynthesis with Diels‐Alder cycloaddition reaction to establish of a powerful synthetic tool which may encourage synthetic organic chemists to use it in the future.