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Platinum Nanosheets between Graphite Layers
Author(s) -
Shirai Masayuki
Publication year - 2019
Publication title -
the chemical record
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.61
H-Index - 78
eISSN - 1528-0691
pISSN - 1527-8999
DOI - 10.1002/tcr.201800098
Subject(s) - platinum , graphite , materials science , hydrogen , hexagonal crystal system , inorganic chemistry , chemical engineering , catalysis , nanotechnology , chemistry , composite material , organic chemistry , crystallography , engineering
Abstract Two‐dimensional platinum nanosheets were obtained by the hydrogen reduction of platinum tetrachloride intercalated between graphite layers, the latter was prepared by the treatment of the mixture of platinum tetrachloride and graphite powder under chlorine atmosphere. The size of platinum nanosheets was 1–3 nm in thickness with a width in the range of 5–300 nm. These nanosheets contain a number of hexagonal holes and edges with an angle of 120°. This review discusses the reduction and oxidation behavior of platinum species and structure of platinum nanosheets between graphite layers. The selective hydrogenation catalyzed by these platinum nanosheets entrapped between the graphite layers is also demonstrated.