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Organocatalytic Hydrophosphonylation Reaction of Carbonyl Groups
Author(s) -
Herrera Raquel P.
Publication year - 2017
Publication title -
the chemical record
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.61
H-Index - 78
eISSN - 1528-0691
pISSN - 1527-8999
DOI - 10.1002/tcr.201600129
Subject(s) - scope (computer science) , carbonyl group , chemistry , group (periodic table) , organocatalysis , organic chemistry , catalysis , stereochemistry , computer science , enantioselective synthesis , programming language
This revision is covering the limited examples reported for a pivotal strategy in the formation of C−P bonds such as the asymmetric organocatalytic hydrophosphonylation of carbonyl groups (Pudovik reaction). The scope and limitations, and the proposed mechanisms for the scarce different possibilities of asymmetric induction are also shown. The recent evolution and future trends of this undeveloped approach are commented.