Divergent Total Synthesis of Atisane‐Type Diterpenoids | Zendy

Zhu Guili | Zendy; Wadavrao Sachin B. | Zendy; Liu Bo | Zendy

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Divergent Total Synthesis of Atisane‐Type Diterpenoids

Author(s) -

Zhu Guili,

Wadavrao Sachin B.,

Liu Bo

Publication year - 2017

Publication title -

the chemical record

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.61

H-Index - 78

eISSN - 1528-0691

pISSN - 1527-8999

DOI - 10.1002/tcr.201600096

Subject(s) - total synthesis , stereochemistry , natural product , type (biology) , chemistry , diterpene , skeleton (computer programming) , terpene , biology , ecology , anatomy

Atisane‐type diterpenoids are the principal constituent of tetracyclic C 20 ‐diterpenoids, widely isolated from the plant kingdom with varying degrees of structural complexity and pharmacological activity. The tetracarbocyclic system with the unique bicyclo[2.2.2]octane skeleton of this natural product family has generated interest within the synthetic community. Divergent total synthesis is an effective tactic to synthesize several atisane‐type diterpenoids using structural interconversion from a common intermediate. This account summarizes the divergent total synthesis of atisane‐type diterpenoids.

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