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The Hiyama Cross‐Coupling Reaction: New Discoveries
Author(s) -
Foubelo Francisco,
Nájera Carmen,
Yus Miguel
Publication year - 2016
Publication title -
the chemical record
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.61
H-Index - 78
eISSN - 1528-0691
pISSN - 1527-8999
DOI - 10.1002/tcr.201600063
Subject(s) - aryl , silanes , coupling reaction , chemistry , combinatorial chemistry , organic synthesis , coupling (piping) , organic chemistry , nanotechnology , biochemical engineering , materials science , engineering , catalysis , alkyl , silane , metallurgy
In this account recent developments in the Hiyama cross‐coupling reaction from 2010 up today are presented. The most important methodology involves formation of biaryl systems by using aryl bromides or iodides and aryl trialkoxy silanes: other variants are far less studied. The most useful procedures are collected paying special attention to the synthetic application of this methodology in synthetic organic chemistry.