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Organo‐ and Organometallic‐Catalytic Intramolecular [1,5]‐Hydride Transfer/Cyclization Process through C(sp 3 )–H Bond Activation
Author(s) -
Kwon Su Jin,
Kim Dae Young
Publication year - 2016
Publication title -
the chemical record
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.61
H-Index - 78
eISSN - 1528-0691
pISSN - 1527-8999
DOI - 10.1002/tcr.201600003
Subject(s) - chemistry , reactivity (psychology) , intramolecular force , hydride , catalysis , group 2 organometallic chemistry , redox , photochemistry , hydrogen bond , reaction mechanism , medicinal chemistry , combinatorial chemistry , hydrogen , acceptor , stereochemistry , organic chemistry , molecule , medicine , alternative medicine , pathology , physics , condensed matter physics
The direct functionalization of C(sp 3 )–H bonds is one of the most synthetically powerful research areas in current organic synthesis. Organocatalytic C(sp 3 )–H bond activation reactions have recently been developed in addition to the traditional metal‐catalyzed C(sp 3 )–H activation reactions. In this review, we aim to give a brief overview of organo‐ and organometallic internal redox cascade reactions with respect to the mechanism, the reactivity of hydrogen donors and acceptors, and the migration modes of hydrogen.