Copper‐Catalyzed Skeletal Rearrangements of   O  ‐Propargylic Oximes via Cleavage of a Carbon–Oxygen Bond | Zendy

Nakamura Itaru | Zendy; Terada Masahiro | Zendy

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Copper‐Catalyzed Skeletal Rearrangements of O ‐Propargylic Oximes via Cleavage of a Carbon–Oxygen Bond

Author(s) -

Nakamura Itaru,

Terada Masahiro

Publication year - 2015

Publication title -

the chemical record

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.61

H-Index - 78

eISSN - 1528-0691

pISSN - 1527-8999

DOI - 10.1002/tcr.201402088

Subject(s) - catalysis , chemistry , copper , bond cleavage , pyridine , cleavage (geology) , oxime , medicinal chemistry , oxygen , carbon fibers , oxygen atom , stereochemistry , organic chemistry , molecule , materials science , fracture (geology) , composite material , composite number

In this account, we describe recent developments in copper‐catalyzed skeletal 2,3‐rearrangement reactions of O ‐propargylic oximes to form four‐membered cyclic nitrones, pyridine N ‐oxides, and amidodienes via N ‐allenylnitrone intermediates. The sequence of events leading up to our encounter with O ‐propargylic oximes is also presented.

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