Professor Tetsuo N ozoe and My Tropylium Ion Chemistry

Needless to say, the discovery of hinokitiol with its “unconventional” aromaticity by Professor Tetsuo N ozoe is one of the most important achievements in organic chemistry in the last century. The essence of this “non‐benzenoid” aromaticity in hinokitiol is of course that of tropolone, and it is further related to the aromaticity of tropone and the tropylium ion, i.e., the cycloheptatrienyl cation. In this account, details of the study conducted by the author's group, particularly on the synthesis and properties of tropylium ion derivatives with various unique structures pursuing the ultimately high carbocation stability, are described.