Premium
Nanoscale polyoxometalate‐based inorganic/organic hybrids
Author(s) -
Song YuFei,
Long DeLiang,
Ritchie Chris,
Cronin Leroy
Publication year - 2011
Publication title -
the chemical record
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.61
H-Index - 78
eISSN - 1528-0691
pISSN - 1527-8999
DOI - 10.1002/tcr.201100002
Subject(s) - polyoxometalate , supramolecular chemistry , hybrid material , covalent bond , surface modification , nanoscopic scale , materials science , nanotechnology , ionic bonding , chemical engineering , chemistry , polymer chemistry , organic chemistry , molecule , catalysis , ion , engineering
The latest advances in the area of polyoxometalate (POM)‐based inorganic/organic hybrid materials prepared by self‐assembly, covalent modification, and supramolecular interactions are presented. This Review is composed of five sections and documents the effect of organic cations on the formation of novel POMs, surfactant encapsulated POM‐based hybrids, polymeric POM/organic hybrid materials, POMs‐containing ionic crystals, and covalently functionalized POMs. In addition to their role in the charge‐balancing, of anionic POMs, the crucial role of organic cations in the formation and functionalization of POM‐based hybrid materials is discussed. DOI 10.1002/tcr.201100002