Premium
Coordination–insertion copolymerization of polar vinyl monomers by palladium catalysts
Author(s) -
Ito Shingo,
Nozaki Kyoko
Publication year - 2010
Publication title -
the chemical record
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.61
H-Index - 78
eISSN - 1528-0691
pISSN - 1527-8999
DOI - 10.1002/tcr.201000032
Subject(s) - copolymer , palladium , monomer , polymer chemistry , phosphine , catalysis , polymer , materials science , transition metal , chemistry , organic chemistry
Random incorporation of polar functional groups into polyolefins and polyketones along with the precise control of incorporation ratios and polymer microstructures is one of the most significant challenges in polymer chemistry. For such a purpose, late‐transition‐metal complexes are often employed as a catalyst for the copolymerization of polar vinyl monomers, because of their high functional group compatibility. This acount describes our contribution to the development of coordination–insertion copolymerization of polar vinyl monomers by palladium catalysts. In particular, the use of palladium/phosphine–sulfonate catalysts enables to incorporate various polar vinyl monomers into polyolefins and polyketones. © 2010 The Japan Chemical Journal Forum and Wiley Periodicals, Inc. Chem Rec 10: 315–325; 2010: Published online in Wiley InterScience ( www.interscience.wiley.com ) DOI 10.1002/tcr.201000032