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Rhodium‐catalyzed restructuring of carbon frameworks
Author(s) -
Murakami Masahiro
Publication year - 2010
Publication title -
the chemical record
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.61
H-Index - 78
eISSN - 1528-0691
pISSN - 1527-8999
DOI - 10.1002/tcr.201000023
Subject(s) - restructuring , rhodium , catalysis , carbon fibers , chemistry , organic chemistry , political science , materials science , composite number , law , composite material
Metal‐catalyzed reactions involving an elementary step which cleaves a carbon‐carbon bond provide unique organic transformations. Restructuring reactions recently developed in our laboratory, through which the carbon framework of a starting substance is restructured into a totally different carbon framework, are discussed, with the possibility of applying such methods to the synthesis of natural products. © 2010 The Japan Chemical Journal Forum and Wiley Periodicals, Inc. Chem Rec 10: 326–331; 2010: Published online in Wiley InterScience ( www.interscience.wiley.com ) DOI 10.1002/tcr.201000023