Premium
Synthesis and Optimization of the Reaction Conditions of Starch Sulfates in Aqueous Solution
Author(s) -
Cui Dapeng,
Liu Mingzhu,
Liang Rui,
Bi Yinghui
Publication year - 2007
Publication title -
starch ‐ stärke
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.62
H-Index - 82
eISSN - 1521-379X
pISSN - 0038-9056
DOI - 10.1002/star.200600567
Subject(s) - starch , chemistry , aqueous solution , potato starch , sodium bisulfite , sodium nitrite , sulfate , sulfation , sodium sulfate , amine gas treating , sodium , nuclear chemistry , inorganic chemistry , organic chemistry , biochemistry
Starch sulfate was prepared by chemical modification of potato starch with trisulfonated sodium amine (N(SO 3 Na) 3 ), which was synthesized by reaction of sodium bisulfite and sodium nitrite in aqueous solution. The factors that could affect the degree of substitution (DS) of potato starch were investigated in detail, which included reaction temperature and time of preparing the sulfating agent, reaction temperature and time of synthesizing the starch sulfate, dosage of sulfating agent and potato starch, pH of sulfation reaction medium, and the ratio of liquid volume to starch mass. A starch sulfate with DS of 2.14 was obtained under optimal conditions. FTIR spectra showed the characteristic absorptions of sulfate ester bonds at 1236 cm −1 and 821 cm −1 .