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Dependence of Thermodynamic Characteristics of Amylose‐Lipid Complex Dissociation on a Variety of Wheat
Author(s) -
Nebesny Ewa,
KwaśniewskaKarolak Izabella,
RosickaKaczmarek Justyna
Publication year - 2005
Publication title -
starch ‐ stärke
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.62
H-Index - 82
eISSN - 1521-379X
pISSN - 0038-9056
DOI - 10.1002/star.200400376
Subject(s) - amylose , enthalpy , starch , differential scanning calorimetry , chemistry , endotherm , swelling , starch gelatinization , food science , wheat starch , dissociation (chemistry) , materials science , thermodynamics , organic chemistry , physics , composite material
Native wheat starch contains amylose‐lipid complexes (AMLs) that are formed both upon biosynthesis of native starch and upon heating of starch slurries at gelatinization temperature and above. These complexes have a detrimental impact on physicochemical properties of starch, because they reduce water binding by starch granules and retard their swelling. An objective of the presented work was to analyze the chemical composition of wheat starch and characterize the thermodynamics of gelatinization of different wheat starches and to evaluate the stability of AMLs derived from these starches with the aid of differential scanning calorimetry (DSC). Grains of eight wheat varieties were used throughout the studies. The gelatinization behavior of the eight wheat varieties examined was similar. The lowest temperature of the onset of gelatinization ( T k = 57.07°C) was found for the Jawa variety, and the highest ( T k = 60.58°C) for the Torka variety. Enthalpy of gelatinization (Δ H k ) of the examined wheat starch preparations ranged from 9.14 J/g (Sakwa) to 11.95 J/g (Elena). Temperature and enthalpy of AMLs dissociation depended on wheat starch variety. During the first heating the temperature of the minimum of the endotherm ( T d ) ranged from 98.41°C to 100.5°C. During the second heating, the minimum was at slightly higher temperatures, varying from 102.02°C to 104.08°C. Enthalpies of AML dissociation (Δ H d ) varied from 1.45 J/g to 2.14 J/g during the first heating. During the second heating the enthalpy values were slightly lower (1.26 J/g to 1.68 J/g). Enthalpies of AML reassociation ranged from 1.29 J/g to 1.72 J/g during the first cooling, and from 1.17 J/g to 1.63 J/g during the second cooling. A correlation was found between the amount of lipids and AML content.