Amylose is not Strictly Linear

Amyloses from selected corn starches were used to measure the glucoses involved in the branching points. The number of glucose α 1,6 glycosidically linked were determined by two different methods: 1) The enzymatic one measures directly quantiatively and specifically the glucoses α, 1,6 linked. 2) The other, a chemical one that measures the different n‐methylated glucoses involved in the terminal, α 1,4 linked and α1,6 linked positions. The results obtained through both methodologies clearly indicate a good correlation. Amylose is not linear. It has very small proportion of branches and they are α1,6 glycosidically linked.