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Equilibrium Reactions of Sugars During Chromatographic Analysis and Their Influence on Elution Time, Peakwidth and Molar Response in Modern Separation Systems
Author(s) -
Verhaar L. A. T.
Publication year - 1982
Publication title -
starch ‐ stärke
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.62
H-Index - 82
eISSN - 1521-379X
pISSN - 0038-9056
DOI - 10.1002/star.19820341007
Subject(s) - elution , chemistry , chromatography , mutarotation , isomerization , chromatographic separation , molar concentration , molar ratio , catalysis , high performance liquid chromatography , organic chemistry
Solutes, especially sugars, can undergo several equilibrium reactions during liquid‐chromatographic elution like mutarotation, lactonization, isomerization, complexation and combinations of these. This can influence chromatographic parameters as: elution time, peak form and ‐width, and molar response.