Premium
An Ultramicroporous Metal–Organic Framework for Sieving Separation of Carbon Dioxide from Methane
Author(s) -
Lin Rui-Biao,
Li Libo,
Alsalme Ali,
Chen Banglin
Publication year - 2020
Publication title -
small structures
Language(s) - English
Resource type - Journals
ISSN - 2688-4062
DOI - 10.1002/sstr.202000022
Subject(s) - methane , carbon dioxide , chemical engineering , adsorption , metal organic framework , molecular sieve , chemistry , carbon fibers , gas separation , materials science , inorganic chemistry , organic chemistry , membrane , biochemistry , composite number , engineering , composite material
Metal–organic frameworks (MOFs) can be rationally constructed with optimal pore structure for highly selective gas separation, but developing efficient adsorbents to fulfill high sieving separation for important processes remains a challenge. Herein, an ultramicroporous MOF [Ca(C 4 O 4 )(H 2 O)] possessing rigid 1D pore channels is applied for high sieving separation of carbon dioxide over methane. This MOF, synthesized from calcium nitrate and squaric acid, contains well‐constrained squarate linkers declining rotations or distortions of organic moieties that could enlarge the pores. These highly rigid pore apertures show sieving size for carbon dioxide capture, but, owing to their size, shape, and rigidity, act as nanosieves to block the diffusion of methane. This material shows large CO 2 uptake capacity of 3.0 mmol g −1 that is higher than some MOF sieves for CO 2 , with negligible coadsorption of CH 4 . The sieving effect of this adsorbent for CO 2 /CH 4 mixture is validated by breakthrough experiments under ambient conditions, showing a productivity of 3012 mmol L −1 for captured CO 2 . Molecular modeling studies reveal the well accommodations of CO 2 molecules in the pore channels of this MOF, facilitating to realize high sieving separation of carbon dioxide from methane.