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Application of Optical Floating Zone Method to Dissolution Kinetics of Inclusions in a Steelmaking Slag
Author(s) -
Sharma Mukesh,
Dabkowska Hanna A.,
Dogan Neslihan
Publication year - 2019
Publication title -
steel research international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.603
H-Index - 49
eISSN - 1869-344X
pISSN - 1611-3683
DOI - 10.1002/srin.201800367
Subject(s) - steelmaking , dissolution , materials science , porosity , slag (welding) , metallurgy , optical microscope , sintering , kinetics , mineralogy , scanning electron microscope , composite material , chemical engineering , chemistry , quantum mechanics , engineering , physics
The dissolution kinetics of micro‐particles (inclusions) in steelmaking slags is investigated using the high temperature confocal scanning laser microscope (HT ‐ CSLM). However, these studies focus on the limited type of inclusions such as Al 2 O 3 , SiO 2, MgO, CaO, and MgAl 2 O 4 . To experimentally study the removability of various problematic inclusions that are not available in the market, optical floating zone and sintering techniques are presented here for the production of high purity micro‐particles. The syntheses of TiO 2 and Al 2 TiO 5 inclusions are employed to demonstrate the advantages and potential of both techniques. These inclusions are then dissolved in the steelmaking slags using CSLM at 1430 °C. In situ observation shows that there is gas evolution during the reaction between slag and Al 2 TiO 5 particles prepared by both techniques. However, the gas evolution is more rapid during the dissolution of particles prepared by sintering and hinders in situ observations and measurements. The optical floating zone technique is capable of preparation of micro‐particles with high purity and less porosity. At 1430 °C, the Al 2 TiO 5 particles do not dissolve at all, whereas TiO 2 particles completely dissolve in 200 s.