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Analysis of the Alkali Flow in Ironmaking Reactors by a Thermochemical Approach: Blast Furnace
Author(s) -
Pichler Anton,
Hauzenberger Franz,
Schenk Johannes,
Stocker Hugo,
Thaler Christoph
Publication year - 2018
Publication title -
steel research international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.603
H-Index - 49
eISSN - 1869-344X
pISSN - 1611-3683
DOI - 10.1002/srin.201700303
Subject(s) - alkali metal , halogen , chlorine , blast furnace , halide , materials science , slag (welding) , chemistry , metallurgy , nuclear engineering , inorganic chemistry , engineering , alkyl , organic chemistry
Elements like potassium and sodium have a negative impact on the blast furnace performance. Therefore, the flow of alkali metals in and out of the reactor has to be controlled. In the furnace, the chemical and physical properties of K and Na lead to the formation of a circulating movement. To point out the characteristics of this alkali‐cycle, a thermochemical model is developed. The program is linked with the databases of Factsage 7.0. Based on a defined standard process, the alkali distribution in particular regions of the reactor is calculated. The results of the calculations show the enrichment of alkalis in the blast furnace, the stability of chosen alkali compounds over the reactor height, and the alkali load in the output flows (slag, metal, and top gas). Furthermore, a modification of the model is done by the addition of halogens (chlorine, fluorine). A significant coherence is observed between the formation of alkali and halogen compounds. The results of the model are compared and confirmed by the validation of investigations on industrial plants.