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Characterization of Passive Film Formed on AISI 316L Stainless Steel after Magnetoelectropolishing in a Broad Range of Polarization Parameters
Author(s) -
Rokosz Krzysztof,
Hryniewicz Tadeusz,
Raaen Steiner
Publication year - 2012
Publication title -
steel research international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.603
H-Index - 49
eISSN - 1869-344X
pISSN - 1611-3683
DOI - 10.1002/srin.201200046
Subject(s) - materials science , electropolishing , polarization (electrochemistry) , corrosion , pitting corrosion , metallurgy , x ray photoelectron spectroscopy , dissolution , electrolyte , analytical chemistry (journal) , metal , austenitic stainless steel , electrode , chemical engineering , chemistry , chromatography , engineering
The aim of the paper is to present the changes in the surface film composition on AISI 316L stainless steel (SS) after electropolishing (EP) and magnetoelectropolishing (MEP) in a broad range of the process conditions. The X‐ray photoelectron spectroscopy surface analyses were performed to reveal the effect of MEP. The EP process has been performed under natural convection (in a stagnant electrolyte), much above the polarization plateau. A series of experiments were carried out on AISI 316L SS samples in accordance with the five‐level composite rotary statistical plan with the variables being the magnetic field intensity B (mT), and the anodic current density i (A dm −2 ). XP high resolution spectra have been obtained on AISI 316L SS surface concerning Fe 2p, Cr 2p, O 1s, S 2p, P 2p, and C 1s, respectively. The Cr:Fe ratio regarding both metallic M and compound X was also studied and calculated. At the end, the summary results of Cr/Fe = f ( B , i ) in relation to the corrosion potential, have been compared. The conclusions, concerning the selection of MEP process conditions, regarding the optimum Cr/Fe ratio and corrosion behavior, have been formulated. It was found the Cr:Fe ratio well correlates with the pitting corrosion potential. MEP process can modify not only the rate of dissolution to a determined extent, but also control the corrosion behavior and Cr:Fe ratio results.