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Activity of Chromium Oxide in CaO‐SiO 2 based Slags at 1873 K
Author(s) -
Morita Kazuki,
Tsukiashi Koji,
Kimura Munekazu,
Sano Nobuo
Publication year - 2005
Publication title -
steel research international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.603
H-Index - 49
eISSN - 1869-344X
pISSN - 1611-3683
DOI - 10.1002/srin.200506009
Subject(s) - chromium , slag (welding) , chromite , refining (metallurgy) , metallurgy , materials science , oxide , redox , solubility , partial pressure , chromium oxide , oxygen , chemistry , organic chemistry
Thermodynamic properties of chromium oxides in molten slags are very important for optimization of stainless steel refining processes as well as reduction processes of chromium ores. The solubility of chromite into molten slags has been found to vary drastically with oxygen partial pressure and slag composition in the former studies by the authors. In the present study, activity data and redox equilibria of chromium oxides measured under moderately reducing conditions, P O2 = 6.95×10 −11 atm, at 1873 K are summarized. For the CaO‐SiO 2 ‐CrO x system, the activity coefficient of chromium oxide increased with increasing basicity and the optimized slag composition for stainless steel refining is assessed as that saturated with CaCr 2 O 4 and Cr 2 O 3 using the phase relations determined. On the other hand, the presence of MgO and Al 2 O 3 brings about different behaviour of chromium oxide activity and redox equilibria and the 44 mass per cent CaO ‐ 39 mass per cent SiO 2 ‐11 mass per cent Al 2 O 3 ‐ 6 mass per cent MgO slag is recommended to reduce the chromium oxidation loss in the practical stainless steel refining process at 1873 K.