Premium
High‐Performance Reticular Porous Perovskite Coating with Wide‐Spectrum Absorption for Photothermal Conversion
Author(s) -
Yu Liuxu,
Zhang Xiangzhao,
Liu Guiwu,
Yang Jian,
Cao Wenkui,
Liu Junlin,
Qiao Guanjun
Publication year - 2021
Publication title -
solar rrl
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.544
H-Index - 37
ISSN - 2367-198X
DOI - 10.1002/solr.202000620
Subject(s) - materials science , photothermal therapy , thermal shock , coating , microstructure , molar absorptivity , optoelectronics , composite material , nanotechnology , optics , physics
Good thermal shock resistance and high absorptivity in a wide spectral range, as the two key aspects of photothermal coating in high‐temperature applications, are seldom realized simultaneously. Herein, it is reported that a reticular porous Ca‐doped LaCrO 3 perovskite photothermal coating fabricated by a simple process presents excellent thermal shock resistance between 1200 °C and room temperature and optical absorptivity of ≈94% in the wavelength range of 0.3–14 μm. The high‐temperature sintering after screen printing triggers significant variations in the microchemistry and microstructure of the Ca‐doped LaCrO 3 coatings, and the experimental analyses and the first‐principles calculation demonstrate that the appropriate doping of Ca 2+ causes lattice distortion, decreases the lattice parameters and bandgap, and effectively enhances interactions between the photon and carrier, resulting in the high optical absorptivity in the visible, near‐, and mid‐infrared ranges. The reticular porous microstructure and interfacial diffusion bonding between the coating and Al 2 O 3 substrate with a gradient transition layer contribute to the high‐temperature thermal shock resistance. Herein, a novel way to fabricate a high‐performance and low‐cost photothermal conversion coating is provided, which presents a broad application prospect in energy harvesters and sensors.