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Multiple Temporal‐Scale Photocarrier Dynamics Induced by Synergistic Effects of Fluorination and Chlorination in Highly Efficient Nonfullerene Organic Solar Cells
Author(s) -
Zhang Kang-Ning,
Niu Meng-Si,
Jiang Zhi-Nan,
Chen Zhi-Hao,
Wang Tong,
Wei Meng-Meng,
Qin Chao-Chao,
Feng Lin,
Qin Wei,
So Shu-Kong,
Hao Xiao-Tao
Publication year - 2020
Publication title -
solar rrl
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.544
H-Index - 37
ISSN - 2367-198X
DOI - 10.1002/solr.201900552
Subject(s) - organic solar cell , exciton , polaron , acceptor , chemical physics , materials science , charge carrier , photovoltaic system , delocalized electron , dielectric , polymer solar cell , chemistry , photochemistry , optoelectronics , polymer , solar cell , organic chemistry , electron , physics , ecology , quantum mechanics , composite material , biology , condensed matter physics
Fluorination and chlorination have yielded a novel class of materials and achieved tremendous progress in enhancing photovoltaic efficiency in organic solar cells (OSCs). However, their effects on photocarrier dynamics remain elusive in these organic photovoltaic systems. Herein, a comprehensive study on the underlying mechanisms is conducted based on a 2 × 2 photovoltaic matrix, consisting of PBDB‐T, PBDB‐T‐2Cl, ITIC, and IT4F. Chlorination of donors enhances exciton migration and relaxation rates and promotes the extraction of polarons. The more efficient charge transfer and a larger proportion of long‐lived polarons are observed in fluorine‐containing acceptor‐based systems, which are in favor of charge generation in the actual devices. According to the enlarged dielectric constant in the PBDB‐T‐2Cl:IT4F blend, the improved exciton delocalization, the decreased exciton binding energy, and Coulomb capture radius are obtained relative to other three binary systems, which can increase charge separation efficiency and reduce the probability of bimolecular recombination. The simultaneous fluorination and chlorination can optimize molecular packing and nanoscale phase separation, facilitating effective exciton diffusion, exciton dissociation, and charge transport. These results highlight the important role of fluorination and chlorination on these fundamental mechanisms, possibly resulting in some new molecular design principles toward high‐performance OSCs.