z-logo
Premium
Perovskite Solar Cells Using Surface‐Modified NiO x Nanoparticles as Hole Transport Materials in n‐i‐p Configuration
Author(s) -
Kaneko Ryuji,
Kanda Hiroyuki,
Sugawa Kosuke,
Otsuki Joe,
Islam Ashraful,
Nazeeruddin Mohammad Khaja
Publication year - 2019
Publication title -
solar rrl
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.544
H-Index - 37
ISSN - 2367-198X
DOI - 10.1002/solr.201900172
Subject(s) - non blocking i/o , materials science , chlorobenzene , nanoparticle , chemical engineering , perovskite (structure) , dopant , layer (electronics) , energy conversion efficiency , nanotechnology , doping , organic chemistry , optoelectronics , chemistry , catalysis , engineering
Modified NiO x nanoparticles (NPs) developed via surface engineering are applied to a hole transport layer (HTL) in n‐i‐p‐structured perovskite solar cells (PSCs). Hexanoic acid (HA) as a surfactant improves the dispersibility of NiO x NPs in chlorobenzene (CB). The conductivity of the NiO x ‐HA film is 1.20 × 10 − 5 S   cm − 1, which is superior to that of 2,2′,7,7′‐tetrakis( N,N ‐di‐ p ‐methoxyphenyl‐amine)‐9,9′‐spirobifluorene (spiro‐OMeTAD) with dopants. The NiO x ‐HA film shows better hole extraction properties compared with the pristine NiO x film. The NiO x ‐HA NPs form closely packed and pinhole‐free films, leading to improved device performance with a power conversion efficiency from 5.5% to 13.1%.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here
Accelerating Research

Address

John Eccles House
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom