Premium
Chemical Dynamics of Back Contact with MoO 3 Interfacial Layer in Kesterite Solar Cells: Microstructure Evolution and Photovoltaic Performance
Author(s) -
Zhang Afei,
Zhou Zhengji,
Zhou Wenhui,
Kou Dongxing,
Meng Yuena,
Qi Yafang,
Yuan Shengjie,
Wu Sixin
Publication year - 2019
Publication title -
solar rrl
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.544
H-Index - 37
ISSN - 2367-198X
DOI - 10.1002/solr.201900131
Subject(s) - kesterite , materials science , annealing (glass) , microstructure , chemical engineering , solar cell , layer (electronics) , work function , energy conversion efficiency , nanotechnology , optoelectronics , metallurgy , czts , engineering
A back contact interface in a kesterite Cu 2 ZnSn(S,Se) 4 (CZTSSe) photovoltaic device plays an important role in fabricating high quality semiconducting photoactive layers and improving carrier extraction efficiency. However, uncontrolled decomposition reactions between the CZTSSe absorber layer and Mo electrode result in high series resistance and recombination at the back interface. The insertion of high work function MoO 3 as an interfacial layer is considered as a promising way to engineer the back contact. This highlights the importance of elucidating the chemistry and dynamics of MoO 3 at the Mo/kesterite interface in the CZTSSe annealing process. Herein, A detailed investigation of the elemental diffusion and chemistry of the back contact with the MoO 3 intermediate layer during selenization is carried out. The results demonstrate that the presence of the MoO 3 interfacial layer largely suppresses the chemical reaction between Mo and CZTSSe in the annealing process, inducing high quality CZTSSe absorbing films with fewer voids and reducing the thickness of MoSe 2 from 209 to 84 nm when the optimized thickness of MoO 3 is 10 nm. This finally leads to the increase in device efficiency from 9.02% to 10.92%, and the best performance where an efficiency of 11.37% is achieved.