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P3HT Molecular Weight Determines the Performance of P3HT:O‐IDTBR Solar Cells
Author(s) -
Khan Jafar Iqbal,
Ashraf Raja Shahid,
Alamoudi Maha A.,
Nabi Mohammed N.,
Mohammed Hamza N.,
Wadsworth Andrew,
Firdaus Yuliar,
Zhang Weimin,
Anthopoulos Thomas D.,
McCulloch Iain,
Laquai Frédéric
Publication year - 2019
Publication title -
solar rrl
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.544
H-Index - 37
ISSN - 2367-198X
DOI - 10.1002/solr.201900023
Subject(s) - photocurrent , acceptor , energy conversion efficiency , polymer solar cell , materials science , polymer , organic solar cell , solar cell , chemical engineering , rhodanine , optoelectronics , chemistry , organic chemistry , composite material , physics , engineering , condensed matter physics
Large‐scale production of organic solar modules requires low‐cost and reliable materials with reproducible batch‐to‐batch properties. In case of polymers, their (photo)physical properties depend strongly on the polymers’ molecular weight (MW). Herein, the impact of the MW of the donor polymer poly(3‐hexylthiophene) (P3HT) on the photophysics is studied in blends with a recently developed rhodanine‐endcapped indacenodithiophene nonfullerene acceptor (IDTBR), a bulk heterojunction (BHJ) system that potentially fulfills the aforementioned criteria for large‐scale production. It is found that the power conversion efficiency (PCE) increases when the weight‐average MW is increased from 17 kDa (PCE: 4.0%) to 34 kDa (PCE: 6.6%), whereas a further increase in MW leads to a reduced PCE of 4.4%. It is demonstrated that the charge generation efficiency, as estimated from time‐delayed collection field experiments, varies with the P3HT MW and is the reason for the differences in photocurrent and device performance. These findings provide insight into the fundamental photophysical reasons of the MW dependence of the PCE, which is taken into account when using polymer‐based nonfullerene acceptor blends in solar cell devices and modules.