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A Bifunctional Saddle‐Shaped Small Molecule as a Dopant‐Free Hole Transporting Material and Interfacial Layer for Efficient and Stable Perovskite Solar Cells
Author(s) -
Lai Xue,
Meng Fei,
Zhang QianQian,
Wang Kai,
Li Gongqiang,
Wen Yaping,
Ma Haibo,
Li Wenhui,
Li Xianqiang,
Kyaw Aung Ko Ko,
Wang Kai,
Sun Xiao Wei,
Du Mengzhen,
Guo Xiao,
Wang Jianpu,
Huang Wei
Publication year - 2019
Publication title -
solar rrl
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.544
H-Index - 37
ISSN - 2367-198X
DOI - 10.1002/solr.201900011
Subject(s) - dopant , bifunctional , energy conversion efficiency , chlorobenzene , materials science , perovskite (structure) , chemical engineering , mesoporous material , aniline , layer (electronics) , doping , nanotechnology , chemistry , crystallography , optoelectronics , organic chemistry , catalysis , engineering
Herein, a new bifunctional saddle‐shaped organic small molecule named 2,2′,7,7′‐tetrakis(N, N‐di‐p‐methoxyphenyl‐aniline)‐α, β‐cycloocta[1,2‐b:4,3‐b′:5,6‐b′:8,7‐b″′]tetrathiophenyl (α, β‐COTh‐Ph‐OMeTAD) is synthesized. When compared with spiro‐OMeTAD, a star hole transporting material (HTM) for highly efficient perovskite solar cells, the new material has a deeper highest occupied molecular orbital (HOMO) energy level of −5.30 eV, and a higher hole mobility of 2.88 × 10 −4 cm 2 V −1 s −1 . With dopant‐free α, β‐COTh‐Ph‐OMeTAD as a HTM and an interfacial layer combinined with chlorobenzene (CB) as the anti‐solvent, mesoporous perovskite solar cells (PSCs) are fabricated, which exhibit a power conversion efficiency (PCE) of 17.22% under AM 1.5 conditions, which is a little higher than that of devices based‐on doped spiro‐OMeTAD under the same conditions, which is 16.83%. Notably, the PSCs devices with dopant‐free α, β‐COTh‐Ph‐OMeTAD as both the HTM and interfacial layer show better stability, and after being stored in dark and dry air without encapsulation for nearly 800 h, the PCE can still be maintained at 86% of the maximum. This opens a new avenue for efficient and stable PSCs by exploring new dopant‐free materials as alternatives to spiro‐OMeTAD.