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Importance of Oxygen Partial Pressure in Annealing NiO Film for High Efficiency Inverted Perovskite Solar Cells
Author(s) -
Zhao Xing,
Chen Jiangzhao,
Park NamGyu
Publication year - 2019
Publication title -
solar rrl
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.544
H-Index - 37
ISSN - 2367-198X
DOI - 10.1002/solr.201800339
Subject(s) - non blocking i/o , materials science , annealing (glass) , partial pressure , tin oxide , energy conversion efficiency , oxygen , photocurrent , doping , analytical chemistry (journal) , chemical engineering , optoelectronics , metallurgy , chemistry , catalysis , biochemistry , organic chemistry , engineering , chromatography
The effect of annealing atmosphere and importance of oxygen partial pressure upon annealing NiO film for achieving high efficiency inverted perovskite solar cells (PSCs) is reported. The solution‐process NiO films are deposited on an FTO (fluorine‐doped tin oxide) substrate and annealed at 400 °C under different atmospheres of air, O 2 , N 2 , and Ar. The devices using air‐ and O 2 ‐annealed NiO films show better photovoltaic performance than the N 2 ‐ and Ar‐annealed ones, mostly due to large difference in photocurrent density ( J sc ) of ≈20 mA cm −2 for air and O 2 vs ≈15 mA cm −2 for N 2 and Ar. Oxygen‐excess condition leads to more p ‐type characteristics along with better electrical and interfacial properties, leading to higher photovoltaic performance. When comparing air and O 2 condition, the air‐annealed NiO film shows slightly better power conversion efficiency (PCE) (15.68% for air vs. 14.93% for O 2 ), being indicative of importance of oxygen partial pressure. By carefully modifying oxygen content, the best photovoltaic performance is achieved from the NiO film annealed at the O 2 /(O 2 +N 2 ) ratio of 30%, delivering a PCE of 16.32%.