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In Situ Ag Nanoparticles Reinforced Pseudo‐Zn–Air Reaction Boosting Ag 2 V 4 O 11 as High‐Performance Cathode Material for Aqueous Zinc‐Ion Batteries
Author(s) -
Li Qian,
Liu Yuyi,
Ma Kaixuan,
Yang Gongzheng,
Wang Chengxin
Publication year - 2019
Publication title -
small methods
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 4.66
H-Index - 46
ISSN - 2366-9608
DOI - 10.1002/smtd.201900637
Subject(s) - electrochemistry , cathode , materials science , nanoparticle , zinc , redox , aqueous solution , electrolyte , chemical engineering , electrode , inorganic chemistry , nanotechnology , chemistry , metallurgy , engineering
Aqueous zinc‐ion batteries (AZIBs), which are low‐cost and environmentally friendly, have been regarded feasible for large‐scale energy storage. But the widespread application of AZIBs is hindered by lack of suitable cathode materials with high capacity and long cycle life. The zinc‐storage mechanisms, especially the formation of basic zinc salt (BZS), are still unclear. Here, Ag 2 V 4 O 11 is developed as a cathode material for AZIBs, which delivers a specific capacity of 213 mA h g −1 and excellent cycling performance (93% capacity retention after 6000 cycles). The reversible formation/decomposition of BZS and reduction/oxidation of metallic Ag are ascertained during the insertion/extraction of Zn(H 2 O) 6 2+ . Remarkably, the phase composition of BZS in Zn(CF 3 SO 3 ) 2 ‐based electrolyte is identified first. The role of in situ formed Ag nanoparticles is simulated by employing the commercial Ag nanoparticles as an additive into the V 2 O 5 ‐based electrodes. The introduction of Ag significantly improves the specific capacity (at least 50% improvement) and accordingly it is proposed that the pseudo‐Zn–air reaction (oxygen reduction reaction‐like redox reaction happens on material surface in a closed system) promotes the electrochemical performance of Ag 2 V 4 O 11 . This work reveals the BZS rather than unknown new phases on the electrode surface and puts forward a possible way in raising electrochemical properties by utilizing the pseudo‐Zn–air reaction.