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Non‐Newtonian Fluid State K–Na Alloy for a Stretchable Energy Storage Device
Author(s) -
Zhang Liyuan,
Li Yuqian,
Zhang Shengzhao,
Wang Xiuli,
Xia Xinhui,
Xie Dong,
Gu Changdong,
Tu Jiangping
Publication year - 2019
Publication title -
small methods
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 4.66
H-Index - 46
ISSN - 2366-9608
DOI - 10.1002/smtd.201900383
Subject(s) - materials science , surface tension , anode , composite number , electrolyte , alloy , nanotechnology , composite material , energy storage , electrode , newtonian fluid , coating , chemistry , power (physics) , physics , quantum mechanics , classical mechanics
Abstract Potassium–sodium alloy (KNA) is defined as an attractive candidate for energy storage devices in space probes. Nevertheless, high surface tension and fluidity of KNA make the electrode difficult to shape which results in unstable electrochemical properties. In this contribution, a low surface tension and paintable non‐Newtonian fluid state KNA and Super P composite (KNA@C) fabricated by a simple stirring strategy is reported. The formation of hydroxides in the KNA@C composite gives rise to stable liquid alloy–electrolyte and liquid alloy–current collector interfaces. Moreover, the KNA@C coating can be well adhered on the surface of the current collector, and keeps stable under bending, folding, and stretching. In addition, an energy conversion device with stretchable and flexible properties is assembled based on the KNA@C anode. Excitingly, the blub keeps shining even extending the device to more than 200% and twisting it to ±90° repeatedly. This research provides an optimistic prospect to achieve stretchable and flexible dendrite‐free alkali metal batteries.

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