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Spinel/Lithium‐Rich Manganese Oxide Hybrid Nanofibers as Cathode Materials for Rechargeable Lithium‐Ion Batteries
Author(s) -
Liu Junxiang,
Wang Jiaqi,
Ni Youxuan,
Zhang Yudong,
Luo Jun,
Cheng Fangyi,
Chen Jun
Publication year - 2019
Publication title -
small methods
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 4.66
H-Index - 46
ISSN - 2366-9608
DOI - 10.1002/smtd.201900350
Subject(s) - spinel , materials science , faraday efficiency , cathode , lithium (medication) , oxide , electrochemistry , chemical engineering , raman spectroscopy , oxygen , electrode , chemistry , metallurgy , medicine , physics , optics , engineering , endocrinology , organic chemistry
Lithium‐rich layered oxides are among the most promising cathode candidates to build high‐energy‐density rechargeable Li‐ion batteries but suffer from capacity/voltage fade, low reversibility, and poor rate capability. Herein, the synthesis and electrochemical application of heterostructured spinel/layered oxide (Li 1.15 Ni 0.20 Mn 0.87 O 2 ) nanofibers as superior cathode materials are reported. The synergistic effect of 1D nanostructure and spinel/layer heterostructure enhances charge transfer, lithium diffusivity, and structural stability, resulting in improved initial Coulombic efficiency (≈100%), rate performance (150 mAh g −1 at 5C), and cyclability (258 mAh g −1 after 70 cycles). In situ X‐ray diffraction and Raman combined with first‐principle calculations reveal that the spinel stabilizes the layered Li‐rich Mn‐based oxide structure via maintaining oxygen vacancy and suppressing the structural variation and oxygen overoxidation.