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UV Laser‐Induced Polyimide‐to‐Graphene Conversion: Modeling, Fabrication, and Application
Author(s) -
Chen Yun,
Long Junyu,
Zhou Shuang,
Shi Dachuang,
Huang Yan,
Chen Xin,
Gao Jian,
Zhao Ni,
Wong ChingPing
Publication year - 2019
Publication title -
small methods
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 4.66
H-Index - 46
ISSN - 2366-9608
DOI - 10.1002/smtd.201900208
Subject(s) - graphene , materials science , polyimide , fabrication , picosecond , nanotechnology , substrate (aquarium) , laser , optoelectronics , optics , medicine , oceanography , alternative medicine , physics , pathology , layer (electronics) , geology
In the past decade, graphene has shown great value in both fundamental sciences and practical applications. In spite of the intense research efforts on achieving chemical‐free, low‐temperature processing of high‐quality graphene, cost‐effective synthetic methods to directly fabricate graphene sheets on a substrate are still lacking. Laser‐induced graphene (LIG) is a recently developed method to directly form graphene from carbon‐rich materials. In this work, combined are theoretical and experimental approaches to systematically investigate the light‐material interactions in LIG fabrication processes. First, developed is a molecular dynamics model to disclose the transient formation process of LIG and identified are the critical parameters that govern this process. Following the theoretical prediction, developed is a system to utilize a picosecond UV laser to directly fabricate graphene from polyimide films at room temperature and under atmospheric pressure. After investigating the effects of the laser processing parameters on the LIG quality and subsequent processing optimization, it is experimentally demonstrated that picosecond UV laser processing can be used to prepare high‐quality LIG. With the newly developed LIG, fabricated is a high‐sensitive proximity sensor.